Control of the Birch Reduction of m-Anisic Acid to Produce Specific 3-Oxocyclohexenecarboxylic Acids

DOI: 10.1055/s-1987-28124

Source and publish data:

Synthesis p. 922 - 924 (1987)

Update date:2022-08-06

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Authors:

Webster, Francis X.

Silverstein, Robert M.

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Article abstract of DOI:10.1055/s-1987-28124

An efficient method is reported of synthesizing relatively large quantities of methyl 3-oxo-1-cyclohexenecarboxylate (2b), a useful dienophile and photoreagent, from m-anisic acid (3) through the Birch reduction.Treating 3 with lithium in liquid ammonia p

Full text of DOI:10.1055/s-1987-28124

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