The Chemistry of Niobium and Tantalum Dithiocarbamato-complexes. Part 5. The Kinetics and Mechanism of the Hydrazine-forming Reactions between 2(μ-N2)> (M=Nb or Ta) and Acid: Rate-limiting Protonation

DOI: 10.1039/DT9900001101

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Journal of the Chemical Society, Dalton Transactions p. 1101 - 1106 (1990)

Update date:2022-08-03

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Authors:

Henderson, Richard A.

Morgan, Susan H.

Stephens, Alan N.

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Article abstract of DOI:10.1039/DT9900001101

The kinetics of the reaction between <3>2(μ-N2)> and HX (M=Nb, X=Cl or Br; M=Ta, X=Cl) to yield and hydrazine have been studied in MeCN at 25.0 deg C.In all cases the multistep mechanism involves rate-limiting protonation of the

Full text of DOI:10.1039/DT9900001101

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