The Chemistry of Niobium and Tantalum Dithiocarbamato-complexes. Part 5. The Kinetics and Mechanism of the Hydrazine-forming Reactions between 2(μ-N2)> (M=Nb or Ta) and Acid: Rate-limiting Protonation

DOI: 10.1039/DT9900001101

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1101 - 1106 (1990)

Update date:2022-08-03

Topics:

Authors:

Henderson, Richard A.

Morgan, Susan H.

Stephens, Alan N.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900001101

The kinetics of the reaction between <3>2(μ-N2)> and HX (M=Nb, X=Cl or Br; M=Ta, X=Cl) to yield and hydrazine have been studied in MeCN at 25.0 deg C.In all cases the multistep mechanism involves rate-limiting protonation of the

Full text of DOI:10.1039/DT9900001101

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:dichloro{tris(diethyl dithiocarbamato)}niobium

Cas No:66985-10-2

R&D Labs maybe for 66985-10-2

Suzhou JMS Chemical Co., Ltd.

Contact:+86-15995924277

Address:WuZhongOu suzhou new south road 89
Hangzhou J&H Chemical Co., Ltd.

website:http://www.jhechem.com/

Contact:+86-571-87396432

Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China
Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

website:http://www.jlpharms.com

Contact:+86-571-86982636

Address:Rm A606, Fuyi Center, jianqiao street, Jianggan Area
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China

Relevant to this article

Oxazolidine Ring Opening and Isomerization to (E)-Imines. Asymmetric Synthesis of Aryl-α-fluoroalkyl Amino Alcohols

Doi:10.1021/ol036486g
(2004)
Carboxylative cyclization of propargylic amines with CO₂ catalyzed by dendritic N-heterocyclic carbene-gold(I) complexes

Doi:10.1016/j.tet.2016.01.016
(2016)
Diastereoselective in and Zn-mediated allylation of pyrazol-4-yl derived (R)-tert-butanesulfinyl imines: Synthesis of enantiomerically pure 6-(pyrazol-4-yl)-piperidin-2,4-diones

Doi:10.1016/j.tetasy.2014.03.003
(2014)
Design, synthesis and biological evaluation of some novel substituted quinazolines as antitumor agents

Doi:10.1016/j.ejmech.2014.04.029
(2014)
A Thermally and Chemically Stable Copper(II) Metal-Organic Framework with High Performance for Gas Adsorption and Separation

Doi:10.1021/acs.inorgchem.1c00357
(2021)
Rational design and bioimaging applications of highly selective fluorescence probes for hydrogen polysulfides

Doi:10.1021/ja502968x
(2014)

Article Doi