CARBON-SILICON BOND CLEAVAGE OF ORGANOTRIALKOXYSILANES AND ORGANOSILATRANES WITH m-CHLOROPERBENZOIC ACID AND N-BROMOSUCCINIMIDE. NEW ROUTE TO PHENOLS, PRIMARY ALCOHOLS AND BROMIDES

DOI: 10.1246/cl.1981.243

Source and publish data:

Chemistry Letters p. 243 - 246 (1981)

Update date:2022-08-05

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Authors:

Hosomi, Akira

Iijima, Susumu

Sakurai, Hideki

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Article abstract of DOI:10.1246/cl.1981.243

Alkyl- and aryltriethoxysilanes undergo oxidative carbon-silicon bond cleavage smoothly with m-chloroperbenzoic acid (MCPBA) to afford the corresponding alcohols.Silatranes similarly gave alcohols and bromides with MCPBA and N-bromosuccinimide, respectively.

Full text of DOI:10.1246/cl.1981.243

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