
Chemistry Letters p. 243 - 246 (1981)
Update date:2022-08-05
Topics:
Hosomi, Akira
Iijima, Susumu
Sakurai, Hideki
Alkyl- and aryltriethoxysilanes undergo oxidative carbon-silicon bond cleavage smoothly with m-chloroperbenzoic acid (MCPBA) to afford the corresponding alcohols.Silatranes similarly gave alcohols and bromides with MCPBA and N-bromosuccinimide, respectively.
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(1979)