Tetrahedron Letters p. 1139 - 1140 (1986)
Update date:2022-08-04
Topics:
Oppolzer, Wolfgang
Stevenson, Thomas
nBu3P-stabilized 1-alkenylcopper reagents undergo efficient 1,4-additions to enoates 1 and 5.Thus, acids 3, 7 or alcohols 4, 8 were obtained in high e.e. with recovery of the auxiliary. 4d was converted to pure (-)-pheromone 13, and 8b gave bromide 14b.
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