Regioselective Incorporation of CO into Enamines by Rhodium-Catalyzed Reaction with a Hydrosilane and CO

DOI: 10.1021/jo00027a002

Source and publish data:

Journal of Organic Chemistry p. 2 - 4 (1992)

Update date:2022-08-02

Topics:

Authors:

Ikeda, Shin-ichi

Chatani, Naoto

Kajikawa, Yasuteru

Ohe, Kouichi

Murai, Shinji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00027a002

In the presence of 2, the reaction of enamines with a hydrosilane and carbon monoxide (140 deg C, 50 atm of CO) resulted in regioselective incorporation of CO into the α-carbon atom to give α-(siloxymethylene) amines, which can be easily conver

Full text of DOI:10.1021/jo00027a002

Products guided by the article

Product name:4-[3-(p-tert.butyl-phenyl)-2-methyl-1-propenyl]-morpholine

Cas No:67305-98-0

R&D Labs maybe for 67305-98-0

NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China

Relevant to this article

Selenium Radical Mediated Cascade Cyclization: Concise Synthesis of Selenated Benzofurans (Benzothiophenes)

Doi:10.1021/acs.orglett.9b02315
(2019)
Radical Polymerization of 5-(4-Acrylamido)-phenyl-10,15,20-triphenylporphyrin

Doi:10.1246/cl.1992.95
(1992)
Optimization of 3-phenylpyrazolo[1,5-a]pyrimidines as potent corticotropin-releasing factor-1 antagonists with adequate lipophilicity and water solubility

Doi:10.1016/j.bmcl.2004.05.019
(2004)
Synthesis and cytotoxic activity of new acridine-thiazolidine derivatives

Doi:10.1016/j.bmc.2012.04.007
(2012)
Doi:10.1021/jm00208a004
(1978)
C-7 modified flavonoids as novel tyrosyl-tRNA synthetase inhibitors

Doi:10.1039/c6ra28061g
(2017)

Article Doi