Regioselective Incorporation of CO into Enamines by Rhodium-Catalyzed Reaction with a Hydrosilane and CO

DOI: 10.1021/jo00027a002

Source and publish data:

Journal of Organic Chemistry p. 2 - 4 (1992)

Update date:2022-08-02

Topics:

Authors:

Ikeda, Shin-ichi

Chatani, Naoto

Kajikawa, Yasuteru

Ohe, Kouichi

Murai, Shinji

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Article abstract of DOI:10.1021/jo00027a002

In the presence of 2, the reaction of enamines with a hydrosilane and carbon monoxide (140 deg C, 50 atm of CO) resulted in regioselective incorporation of CO into the α-carbon atom to give α-(siloxymethylene) amines, which can be easily conver

Full text of DOI:10.1021/jo00027a002

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