Journal of Organometallic Chemistry p. 403 - 412 (1981)
Update date:2022-08-03
Topics:
Walther, Dirk
Zeigan, Dieter
Some 1-azabutadienes react with 1,3-dienes at the central atom nickel(0) by oxidative coupling to form new binuclear nickel(II) complexes, in which the central unit is a diazadinickelacyclooctadiene.The structures of these compounds are investigated by spectroscopic measurements, especially by 13C NMR.A possible mechanism for these coupling reactions is discussed.The reverse reaction, a reductive decoupling of the systems, can be realised with strong ?-acid ligands or by thermal reactions.
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