
Journal of the American Chemical Society p. 6259 - 6267 (1980)
Update date:2022-08-05
Topics:
Condran, Patrick
Hammond, Milton L.
Mourino, Antonio
Okamura, William H.
The thermally induced <1,5>-sigmatropic hydrogen shift of the diastereomeric vitamin D type vinylallenols 6a (1R,6R), 6b (1R,6S), 7a (1S,6S) and vinylallenols 5a (6R) and 5b (6S) were studied.The 1S,6S (7b) and 1R,6R(6a) alcohols afforded ca. 60percent yi
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