Optical Resolution of (2-Aminoethyl)butylphenylphosphine and the Absolute Configuration Assigned on the Basis of Circular Dichroism Spectra of Its Palladium(II) Complexes

DOI: 10.1246/bcsj.53.3715

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3715 - 3716 (1980)

Update date:2022-08-03

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Authors:

Kinoshita, Isamu

Kashiwabara, Kazuo

Fujita, Junnosuke

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Article abstract of DOI:10.1246/bcsj.53.3715

(2-Aminoethyl)butylphenylphosphine was resolved with (+)_D-di-μ-chlorobis<(S)-N,N-dimethyl-α-methylbenzylamine-2C,N>dipalladium(II), and the absolute configuration of the chiral phosphorus atom was assigned on the basis of the circular dichroism spectra of dichloro palladium(II) complexes with the resolved aminophosphine

Full text of DOI:10.1246/bcsj.53.3715

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