Optical Resolution of (2-Aminoethyl)butylphenylphosphine and the Absolute Configuration Assigned on the Basis of Circular Dichroism Spectra of Its Palladium(II) Complexes

Article abstract of DOI:10.1246/bcsj.53.3715

(2-Aminoethyl)butylphenylphosphine was resolved with (+)_D-di-μ-chlorobis<(S)-N,N-dimethyl-α-methylbenzylamine-2C,N>dipalladium(II), and the absolute configuration of the chiral phosphorus atom was assigned on the basis of the circular dichroism spectra of dichloro palladium(II) complexes with the resolved aminophosphine