Bulletin of the Chemical Society of Japan p. 1768 - 1772 (1993)
Update date:2022-08-04
Topics:
Tamiaki, Hitoshi
Kiyomori, Ayumu
Maruyama, Kazuhiro
Several benzophenone-β-turned dipeptide-alkyl chain molecules were prepared.In acetonitrile, intramolecular photochemical reaction of the synthetic molecules was investigated.The photoexcited benzophenone moiety abstracted selectively a hydrogen of the alkyl chain in the molecule.Such a site selectivity showed that the β-turned conformation might be rigid enough for the hydrogen abstraction in the excited state.
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