144. Ueber die Stereoselektivitaet der α-Alkylierung von (1R,2S)(+)-cis-2-Hydroxy-cyclohexancarbonsaeureaethylester

Article abstract of DOI:10.1002/hlca.19800630605

In continuation of our work on the stereoselectivity of the α-alkylation of β-hydroxyesters <1> <2>, we studied this reaction with the title compound (+)-2.The latter was prepared through reduction of 1 with baker's yeast.Alkylation of the dianion of (+)-