STEREOHOMOGENEUS SYNTHESIS OF (E)- AND (Z)-CROTYLTRIFLUOROSILANES AND HIGHLY STEREOSELECTIVE ALLYLATION OF ALDEHYDES

DOI: 10.1016/S0040-4039(01)80370-1

Source and publish data:

Tetrahedron Letters p. 1099 - 1102 (1989)

Update date:2022-08-03

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Authors:

Kira, Mitsuo

Hino, Takakazu

Sakurai, Hideki

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Article abstract of DOI:10.1016/S0040-4039(01)80370-1

Stereohomogeneus (E)- and (Z)-crotyltrifluorosilanes were prepared and used for the highly diastereoselective synthesis of threo- and erythro-β-methylhomoallyl alcohols, respectively, from aldehydes in the presence of fluoride ions.The mechanism of the reaction was discussed.

Full text of DOI:10.1016/S0040-4039(01)80370-1

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