Tetrahedron Letters p. 1099 - 1102 (1989)
Update date:2022-08-03
Topics:
Kira, Mitsuo
Hino, Takakazu
Sakurai, Hideki
Stereohomogeneus (E)- and (Z)-crotyltrifluorosilanes were prepared and used for the highly diastereoselective synthesis of threo- and erythro-β-methylhomoallyl alcohols, respectively, from aldehydes in the presence of fluoride ions.The mechanism of the reaction was discussed.
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