Phenyliodonium Bis(Perfluoroalkanesulphonyl) Methide; Synthesis and Reactions as a Precursor of Bis(Perfluoroalkanesulphonyl) Carbene

DOI: 10.1039/c39900001459

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1459 - 1460 (1990)

Update date:2022-08-03

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Authors:

Zhu, Shi-zheng

Chen, Qing-yun

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Article abstract of DOI:10.1039/c39900001459

Photoreaction of the title compound PhI⁺^-C(R_FSO2)2 which was synthesised by the reaction of bis(perfluoroalkanesulphonyl) methane with diacetoxyiodobenzene, with alkene, methanol, bromine and benzene gave corresponding addition or insertion products, via the bis(perfluoroalkanesulphonyl) carbene, (R_FSO2)C: intermediate.

Full text of DOI:10.1039/c39900001459

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