Tetrahedron Letters p. 6321 - 6324 (1988)
Update date:2022-08-05
Topics:
Ito, Yoshihiko
Sawamura, Masaya
Kobayashi,Masaaki
Hayashi, Tamio
Aldol reaction of N,N-dialkyl-α-isocyanoacetamides with primary alkyl aldehydes in the presence of 0.5-1 molpercent of a chiral (aminoalkyl)ferrocenylphosphine-gold(I) catalyst proceeded with high enantio- and diastereoselectivity to give trans-5-alkyl-2-oxazoline-4-carboxamides of up to 98.6percent ee, which were converted into optically active threo-β-hydroxyamino acids.
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