Formal C-H insertion of diketocarbene generated by rhodium(II)-catalyzed decomposition of diazodimedone into a benzene molecule

DOI: 10.1007/BF01434000

Source and publish data:

Russian Chemical Bulletin p. 471 - 473 (1996)

Update date:2022-08-03

Topics:

Authors:

Chapyshev

Nakano Nakano

Ibata Ibata

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF01434000

Diketocarbene generated by rhodium(II) acetate-catalyzed decomposition of diazodimedone reacts with benzene at room temperature to give 5,5-dimethyl-2-phenylcyclohexane-1,3-dione in 88 % yield.

Full text of DOI:10.1007/BF01434000

Products guided by the article

Product name:5,5-dimethyl-2-phenylcyclohexane-1,3-dione

Cas No:6853-00-5

R&D Labs maybe for 6853-00-5

Heliosense Biotechnologies, Inc.

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Dongying J&M Chemical Co., Ltd,

Contact:546-8551108

Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China

Relevant to this article

Enantioselective vinylogous aldol reaction of acylphosphonates with 3-alkylidene oxindoles

Doi:10.1039/d1ob00140j
(2021)
Poly(oxyethylene)-substituted copper and lutetium phthalocyanines

Doi:10.1021/jp960504c
(1996)
Synthesis of benzotriazoles derivatives and their dual potential as α-amylase and α-glucosidase inhibitors in vitro: Structure-activity relationship, molecular docking, and kinetic studies

Doi:10.1016/j.ejmech.2019.111677
(2019)
Synthesis of heptacosapeptide (AA 111 -AA 137 ) of the -chain of a human immunoglobulin (IgGl) using N-tert-butyloxycarbonyl-L-amino acid pentachlorophenyl esters.

Doi:10.1002/jps.2600620639
(1973)
Doi:10.1021/ja00747a031
(1971)
Intramolecular borylation reaction catalyzed by Lewis acid: Preparation of 1H-2,1-benzazaborole derivatives

Doi:10.1039/b003999n
(2000)

Article Doi