Formal C-H insertion of diketocarbene generated by rhodium(II)-catalyzed decomposition of diazodimedone into a benzene molecule

DOI: 10.1007/BF01434000

Source and publish data:

Russian Chemical Bulletin p. 471 - 473 (1996)

Update date:2022-08-03

Topics:

Authors:

Chapyshev

Nakano Nakano

Ibata Ibata

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Article abstract of DOI:10.1007/BF01434000

Diketocarbene generated by rhodium(II) acetate-catalyzed decomposition of diazodimedone reacts with benzene at room temperature to give 5,5-dimethyl-2-phenylcyclohexane-1,3-dione in 88 % yield.

Full text of DOI:10.1007/BF01434000

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