Tetrahedron Letters p. 493 - 496 (1981)
Update date:2022-08-04
Topics:
Kurobane, Itsuo
Hutchinson, C. Richard
Vining, Leo C.
Analyses of the regiochemistry of <13C>acetate incorporation into fulvic acid (2) by Penicillium brefeldianum indicates that the metabolite is biosynthesized via a heptaketide intermediate assembled as a single chain of seven C2 units rather than from two smaller polyketide chains.This information favours a route leading through common C14 intermediates to the three fungal metabolites, citromycetin, fulvic acid and fusarubin.
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