Angewandte Chemie - International Edition p. 14140 - 14142 (2013)
Update date:2022-08-02
Topics:
Ng, Yong Xiang
Mathey, Francois
User friendly P-C: Electrophilic terminal phosphinidene complexes [RP-W(CO)5] react with Ar-B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P-C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P-H bond that can be used for further transformations. Copyright
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