BIMETALLIC ACTIVATION OF COORDINATED LIGANDS. REACTIONS OF THE LEWIS ACID (η-C5H5)(CO)3Mo+ PF6- WITH ORGANO-IRON AND -MOLYBDENUM η1-METHOXYMETHYL AND ETHYL COMPLEXES

DOI: 10.1016/0022-328X(85)88052-9

Source and publish data:

Journal of Organometallic Chemistry p. 45 - 58 (1985)

Update date:2022-08-05

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Authors:

Markham, James

Tolman, William

Menard, Kevin

Cutler, Alan

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Article abstract of DOI:10.1016/0022-328X(85)88052-9

The organometallic Lewis acid Cp(CO)3Mo⁺ PF6^- reacts with organo-iron and -molybdenum methoxymethyl and ethyl complexes via methoxide and/or hydride abstraction.Thus, Cp(CO)3MoCH2OCH3 and Cp(CO)(L)FeCH2OCH3 (L = CO, PPh3) produce the

Full text of DOI:10.1016/0022-328X(85)88052-9

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Product name:((C₅H₅)Mo(CO)3)2H⁽¹⁺⁾*PF₆^(1-)=[((C₅H₅)Mo(CO)3)2H]PF₆

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