Tetrahedron Letters p. 5161 - 5164 (1997)
Update date:2022-08-05
Topics:
Yachi, Kentaro
Maeda, Katsuya
Shinokubo, Hiroshi
Oshima, Koichiro
Whereas erythro-iodohydrin derivatives provided (E)-alkenes with high stereoselectivity upon treatment with titanium tetrachloride in the presence of allyltrimethylsilane, the corresponding threo isomers afforded (Z)-alkenes exclusively. The reaction was applied to the stereoretentive conversion of epoxides to alkenes.
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