Journal of Physical Chemistry A p. 3485 - 3492 (2004)
Update date:2022-07-30
Topics:
Pomestchenko, Irina E.
Castellano, Felix N.
Photophysical properties of a multichromophoric platinum (II) complex were investigated in different solvents of varying polarity. It was found that energy of the metal-to-charge transfer (MLCT) increased with the raise in solvent polarity. It was observed that metal-perturbed triplet intraligand (IL) state present within the molecule was invariant to the solvent polarity. The results show that decay of the excited state is directly influenced by the MLCT state.
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Doi:10.1016/j.poly.2004.01.002
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