Chinese Journal of Chemistry p. 916 - 920 (2018)
Update date:2022-08-05
Topics:
Wang, Gaonan
Gan, Yi
Liu, Yuanhong
The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni(cod)2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or arylboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of allylic alcohols.
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