HIGHLY SELECTIVE, KINETICALLY CONTROLLED ENOLATE FORMATION USING LITHIUM DIALKYLAMIDES IN THE PRESENCE OF TRIMETHYLCHLOROSILANE

DOI: 10.1016/S0040-4039(00)99920-9

Source and publish data:

Tetrahedron Letters p. 495 - 498 (1984)

Update date:2022-08-05

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Authors:

Corey, E. J.

Gross, Andrew W.

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Article abstract of DOI:10.1016/S0040-4039(00)99920-9

The deprotonation of ketones and esters with lithium dialkylamides in the presence of trimethylchlorosilane leads to enhanced selectivity for the kinetically generated enolate.Lithium t-octyl-t-butylamide is shown to be superior to lithium diisopropylamid

Full text of DOI:10.1016/S0040-4039(00)99920-9

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