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Studies of Vitamin D Oxidation. 3. Dye-Sensitized Photooxidation of Vitamin D and Chemical Behavior of Vitamin D 6,19-Epidioxides

DOI: 10.1021/jo00168a020

Source and publish data:

Journal of Organic Chemistry p. 3477 - 3483 (1983)

Update date:2022-08-05

Topics:

Authors:

Yamada, SachikoYamada, Sachiko

Nakayama, KeikoNakayama, Keiko

Takayama, HiroakiTakayama, Hiroaki

Itai, AkikoItai, Akiko

Iitaka, YoichiIitaka, Yoichi

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Article abstract of DOI:10.1021/jo00168a020

Dye-sensitized photooxidation of vitamin D and the chemical reactions of the resulting oxidation products have been studied in detail.Vitamin D undergoes 1,4-cycloaddition and ene-type reactions with singlet oxygen to yield two C(6) epimers of 6,19-epidio

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Full text of DOI:10.1021/jo00168a020

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