
Bulletin of the Chemical Society of Japan p. 455 - 457 (1980)
Update date:2022-08-05
Topics:
Ogawa, Seiichiro
Toyokuni, Tatsushi
Omata, Masaji
New cyclitols, validatol and deoxyvalidatol, derived by hydrogenolysis of antibiotic validamycin A, were synthesized as the racemates from readily available tri-O-acetyl-(1,3/2,4,6)-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol.
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