Tetrahedron Letters p. 551 - 554 (1982)
Update date:2022-08-04
Topics:
Hosomi, Akira
Iguchi, Hirokazu
Sasaki, Jun-ichi
Sakurai, Hideki
2-Trimethylsilylmethyl-1,3-butadiene undergoes highly regioselective Diels-Alder reactions with dienophiles such as acrolein and methyl vinyl ketone catalyzed by aluminium chloride in which the "para" isomers are obtained almost exclusively.The adducts are converted readily to a variety of naturally occurring mono and sesquiterpenes.
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