NOUVELLE VOIE D'ACCES A DES ALLENES ET VINYLALLENES ENANTIOMERIQUEMENT ENRICHIS.

DOI: 10.1016/0040-4039(81)80160-8

Source and publish data:

Tetrahedron Letters p. 103 - 106 (1981)

Update date:2022-09-26

Topics:

Authors:

Verniere, Catherine

Cazes, Bernard

Gore, Jacques

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Article abstract of DOI:10.1016/0040-4039(81)80160-8

The reduction of three racemic propargylic bromides by Hiyama's reagent (CrCl2 in THF) in the presence of protonic chiral reagents and HMPT efficiently affords optically active allenic compounds with an enantiomeric purity of 15-25 percent.

Full text of DOI:10.1016/0040-4039(81)80160-8

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