Tetrahedron Letters p. 103 - 106 (1981)
Update date:2022-09-26
Topics:
Verniere, Catherine
Cazes, Bernard
Gore, Jacques
The reduction of three racemic propargylic bromides by Hiyama's reagent (CrCl2 in THF) in the presence of protonic chiral reagents and HMPT efficiently affords optically active allenic compounds with an enantiomeric purity of 15-25 percent.
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