Journal of Molecular Structure p. 159 - 162 (1982)
Update date:2022-08-04
Topics:
Church, S. P.
Poliakoff, M.
Timney, J. A.
Turner, J. J.
The radical Mn(CO)5 is generated by the photolysis of HMn(CO)5 in a low temperature solid CO matrix.It is characterized by IR spectroscopy, including isotopic studies, and it is shown to have a visible absorption band at ca. 800 nm, close to that assigned to Mn(CO)5 in room-temperature studies.
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