Preparation of Alkyl-substituted Partial Trimethylsilyl Silicates from Olivine

DOI: 10.1039/DT9810001957

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1957 - 1960 (1981)

Update date:2022-08-03

Topics: Characterization Workup and Purification

Authors:

Kuroda, Kazuyuki

Koike, Tetsuhiro

Kato, Chuzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810001957

The direct trimethylsilylation reaction of olivine has yielded partial trimethylsilyl derivatives of ortho- and di-silicates whose unsilylated silanol groups have been esterified with the alcohol used as the organic solvent in the trimethylsilylating reagent.Gas chromatographic-mass spectroscopic measurements indicate the presence of the tri-, di-, and mono-alkyl-substituted trimethylsilyl derivatives of monosilicic acid in addition to the fully silylated monomeric derivative .Dimeric derivatives have also been detected which contain both the completely trimethylsilylated derivative and alcohol-esterified derivatives .The ratio of the esterified products varies with the volume of alcohol or water in the silylating reagent as well as the reaction time.

Full text of DOI:10.1039/DT9810001957

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-isopropoxy-1,1,1,7,7,7-hexamethyl-3,5,5-tris(trimethylsiloxy)tetrasiloxane

Cas No:71579-69-6

R&D Labs maybe for 71579-69-6

Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Nanjing Xi Ze Biological Technology Co., Ltd

Contact:86-025-66023220

Address:Address: Nanjin Qixia District Maigaoqiao R & D base in Pioneer Park Chun Yin Road 18-A928
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China

Relevant to this article

CHIRAL, BIOMIMETIC TOTAL SYNTHESIS OF (-)-APLYSISTATIN.

Doi:10.1016/S0040-4039(00)85676-2
(1982)
Doi:10.1021/jm00197a002
(1979)
Enolboration. 5. An Examination of the Effects of Amine, Solvent, and Other Reaction Parameters on the Stereoselective Enolboration of Ketones with Various Chx2BX Reagents. An Optimized Procedure To Achieve the Stereoselective Synthesis of E Enol Borinate

Doi:10.1021/jo00077a046
(1993)
Asymmetric synthesis of enantiomerically enriched atropisomeric amides by desymmetrisation of N,N-dialkylmesitamides

Doi:10.1039/b008678i
(2001)
Biflora-4,10(19),15-triene: A New Diterpene from a Termite Soldier (Isoptera Termitidae Termitinae)

Doi:10.1021/jo01289a048
(1980)
Efficient synthesis of nucleoside 5′-triphosphates and their β,γ-bridging oxygen-modified analogs from nucleoside 5′-phosphates

Doi:10.1016/j.tetlet.2014.02.031
(2014)

Article Doi