Tetrahedron Letters p. 5047 - 5050 (1982)
Update date:2022-08-03
Topics:
Solladie, Guy
Greck, Christine
Demailly, Gilles
Solladie-Cavallo, Arlette
It is shown that reductions of β-ketosulfoxides of identical chirality (R) at sulfur, lead to reduction products of opposite stereochemistry according to the reducing agent used.The high enantiomeric excesses obtained (80 to 100percent) provide a general route to both enantiomers of methylcarbinols from the corresponding esters.
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