Tetrahedron Letters p. 5047 - 5050 (1982)
Update date:2022-08-03
Topics:
Solladie, Guy
Greck, Christine
Demailly, Gilles
Solladie-Cavallo, Arlette
It is shown that reductions of β-ketosulfoxides of identical chirality (R) at sulfur, lead to reduction products of opposite stereochemistry according to the reducing agent used.The high enantiomeric excesses obtained (80 to 100percent) provide a general route to both enantiomers of methylcarbinols from the corresponding esters.
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Doi:10.1515/znb-2007-0509
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(1979)Doi:10.1016/j.bmc.2004.03.054
(2004)Doi:10.1021/acs.orglett.1c00238
(2021)Doi:10.1016/j.carbpol.2013.04.049
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(2004)
