Journal of the Chemical Society. Perkin transactions I p. 1064 - 1067 (1981)
Update date:2022-08-05
Chambers, Richard D.
Lindley, Andrew A.
Fielding, Harold C.
Moilliet, John S.
Whittaker, Graham
Passage of perfluoro-3,4-dimethylhex-3-ene over iron or platinum at elevated temperatures leads to defluorination and fragmentation, giving fluorinated dienes, e.g. perfluoro-2,3-dimethylbutadiene (over Pt) and perfluoro-3,4-dimethylhexa-2,4-diene (over Fe), together with other products.Similar reactions with other fluorinated alkenes and the variation between fragmentation and fluorination is rationalised on the basis of the metal used, etc.The fluoride induced reaction between perfluoropropene and perfluorobut-2-ene gives perfluoro-2,3-dimethylpent-2-ene.
View MoreContact:0512-63006287
Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Yicheng Goto Pharmaceuticals Co.,Ltd.
Contact:+86 710 3423122
Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
SJZ Chenghui Chemical Co., Ltd.
Contact:86-311-87713916
Address:no.368 youyi north avenue
Zibo Ocean International Trade Co.,Ltd(expird)
Contact:+86 533 5160706
Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Shandong Yubin Chemical CO.,LTD
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone，262737 shangdong，china
Doi:10.1016/0040-4020(81)80011-7
(1981)Doi:10.1002/chem.201002483
(2011)Doi:10.1021/om0401096
(2004)Doi:10.1021/jo00173a039
(1983)Doi:10.1016/S0040-4039(00)86848-3
(1982)Doi:10.1016/S0040-4039(00)86991-9
(1982)
