Enantiospecific Synthesis of (3S,4S)-Statine and Its Analogue from D-Glucosamine as a Chiral Pool

DOI: 10.1246/cl.1992.2265

Source and publish data:

Chemistry Letters p. 2265 - 2268 (1992)

Update date:2022-07-30

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Authors:

Shinozaki, Katsuo

Mizuno, Kazuhiro

Oda, Hirohisa

Masaki, Yukio

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Article abstract of DOI:10.1246/cl.1992.2265

The C(6)-carbon degradation and elimination C(4)-hydroxy group of D-glucosamine were achieved in 8-steps and 30percent overall yield to furnish (4R,5S)-5-vinyl-2-oxazolidinone-4-carbaldehyde dimethyl acetal, which was utilized as a key intermediate for en

Full text of DOI:10.1246/cl.1992.2265

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