Anion-Mediated Fragmentation Reactions. Mechanistic and Synthetic Aspects of the Fragmentation and Rearrangement Reactions of Pyrimidinedione-Alkyne Photoadducts

DOI: 10.1021/jo00162a008

Source and publish data:

Journal of Organic Chemistry p. 2337 - 2346 (1983)

Update date:2022-08-04

Topics:

Authors:

Kaminski, Victor V.

Comber, Robert N.

Wexler, Allan J.

Swenton, John S.

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Article abstract of DOI:10.1021/jo00162a008

The acetone-sensitized photocycloadditon reactions of uracil, thymine, 5-fluorouracil, and 5-(trimethylsilyl)uracil with alkynes afford 2,4-diazabicyclo<4.2.0>oct-7-ene-3,5-diones.It is noteworthy that 5-(trimethylsilyl)uracil gives very high yields in th

Full text of DOI:10.1021/jo00162a008

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