Intermolecular Couplings between Vinyl Triflates and Allylic Cuprates: A Mild and Rapid Atypical Route to 1,4-Dienes

DOI: 10.1021/jo00293a002

Source and publish data:

Journal of Organic Chemistry p. 1695 - 1696 (1990)

Update date:2022-08-02

Topics:

Authors:

Lipshutz, Bruce H.

Elworthy, Todd R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00293a002

Tratment of vinyl triflates with several different allylic ligands leads to coupling products in good yields.Cuprates containing allyl, methallyl, crotyl, and prenyl groups all participate in these reactions which take place instantly at low temperatures.

Full text of DOI:10.1021/jo00293a002

Products guided by the article

Product name:(6-methyl-2,5-heptadienyl)benzene

Cas No:72486-23-8

R&D Labs maybe for 72486-23-8

NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China

Relevant to this article

A systematic study of steric control of the thiocyanate's bonding mode in [Pd(substituted diamine)(thiocyanate)₂] and [Pd(substituted diamine)₂] (SCN)₂ complexes

Doi:10.1016/S0020-1693(00)81895-2
(1982)
Dibromomethane as one-carbon source in organic synthesis: A versatile methodology to prepare the cyclic and acyclic α-methylene or α-keto acid derivatives from the corresponding terminal alkenes

Doi:10.1016/j.tet.2004.04.013
(2004)
Direct regioselective chlorination of unprotected hexitols and pentitols by Vilsmeier and Haack's salt

Doi:10.1016/S0040-4039(00)61228-5
(1992)
Vinylation of α-Aminoazoles with Triethylamine: A General Strategy to Construct Azolo[1,5-a]pyrimidines with a Nonsubstituted Ethylidene Fragment

Doi:10.1021/acs.orglett.1c00571
(2021)
Doi:10.1055/s-1979-28886
(1979)
Doi:10.1021/jo01059a027
(1962)

Article Doi