Intermolecular Couplings between Vinyl Triflates and Allylic Cuprates: A Mild and Rapid Atypical Route to 1,4-Dienes

DOI: 10.1021/jo00293a002

Source and publish data:

Journal of Organic Chemistry p. 1695 - 1696 (1990)

Update date:2022-08-02

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Authors:

Lipshutz, Bruce H.

Elworthy, Todd R.

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Article abstract of DOI:10.1021/jo00293a002

Tratment of vinyl triflates with several different allylic ligands leads to coupling products in good yields.Cuprates containing allyl, methallyl, crotyl, and prenyl groups all participate in these reactions which take place instantly at low temperatures.

Full text of DOI:10.1021/jo00293a002

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