Chemistry of α-Aminonitriles. Aldomerisation of Glycolaldehyde Phosphate to rac-Hexose 2,4,6-triphosphates and (in Presence of Formaldehyde) rac-Pentose 2,4-diphosphates: rac-Allose 2,4,6-Triphosphate and rac-Ribose 2,4-Diphosphate Are the Main Reaction P

DOI: 10.1002/hlca.19900730526

Source and publish data:

Helvetica Chimica Acta p. 1410 - 1468 (1990)

Update date:2022-08-15

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Authors:

Mueller, Daniel

Pitsch, Stefan

Kittaka, Atsushi

Wagner, Ernst

Wintner, Claude E.

Eschenmoser, Albert

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Article abstract of DOI:10.1002/hlca.19900730526

Glycolaldehyde phosphate aldomerizes in aqueous NaOH solution to a product mixture containing the racemates of the two diastereoisomeric tetrose 2,4-diphosphates and eight hexose 2,4,6-triphosphates.At room temperature in the absence of air and after 7 da

Full text of DOI:10.1002/hlca.19900730526

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