Journal of Organic Chemistry p. 1189 - 1196 (1980)
Update date:2022-08-04
Topics:
Degrand, Chantal
Compagnon, Paul-Louis
Belot, Gerard
Jacquin, Dominique
The one-step synthesis of cyclic compounds is achieved in a few cases by electroreduction of unsaturated compounds in DMF, at a mercury pool cathode, in the presence of a more difficulty reducible dielectrophile.Unsaturated compounds include activated olefins, aromatic Schiff bases, ketones, and azo, nitroso, and nitro compounds.Four dielectrophiles are used; they are tri- or tetramethylene bromide, succinyl chloride, and 4-bromobutyryl chloride.The electrochemical synthesis of derivatives of cyclohexane, piperidine, pyrrolidine, hexahydropyridazine, tetrahydropyridazinone, tetrahydropyridazinedione, tetrahydrooxazine, isoxazolidine, and spirolactone can be succesfully performed.Their yields range from 8 to 78percent depending on competitive reactions.Results of chemical reduction by alkali metals and electrochemical reduction are compared.
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Doi:10.1055/s-1979-28851
(1979)Doi:10.1021/jo00028a053
(1992)Doi:10.1016/0277-5387(95)00321-5
(1996)Doi:10.1021/ja045558b
(2005)Doi:10.2174/092986712803251557
(2012)Doi:10.1016/s0020-1693(00)00190-0
(2000)