Journal of the American Chemical Society p. 3763 - 3767 (1983)
Update date:2022-08-03
Topics:
Guarr
Buhks
McLendon
The deuterium isotope effect on the thermodynamic driving force is discussed. Theory correctly predicts a decrease in the kinetic isotope effect as the reaction driving force increases. The observed isotope effect for replacement of H//2O by D//2O is significantly larger than predicted even after correcting for the solvent dependence of the reaction driving force.
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Doi:10.1016/S0040-4039(00)72905-4
(1966)Doi:10.1021/acs.orglett.0c02799
(2020)Doi:10.3390/molecules21050636
(2016)Doi:10.1021/acs.joc.9b00801
(2019)Doi:10.1007/s10593-013-1381-3
(2013)Doi:10.1021/ic302759k
(2013)
