Isomerization of N-Allylamides and -imides to Aliphatic Enamides by Iron, Rhodium, and Ruthenium Complexes

DOI: 10.1021/jo01299a021

Source and publish data:

Journal of Organic Chemistry p. 2139 - 2145 (1980)

Update date:2022-09-26

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Authors:

Stille, J. K.

Becker Y.

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Article abstract of DOI:10.1021/jo01299a021

Substituted aliphatic N-propenylamides and -imides are readily sythesized from N-allylamides by double bond migration induced by rhodium or ruthenium hydrides.N-Propenylimides can be prepared from allylimides only in the presence of iron pentacarbonyl.

Full text of DOI:10.1021/jo01299a021

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