HALOGEN EXCHANGE EQUILIBRIA OF CHLOROFLUOROOLEFINS

DOI: 10.1016/S0022-1139(00)82180-6

Source and publish data:

Journal of Fluorine Chemistry p. 77 - 87 (1990)

Update date:2022-08-02

Topics:: Authors:

Coulson, D. Robert

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Article abstract of DOI:10.1016/S0022-1139(00)82180-6

The thermochemical properties of the following reactions were determined using either AlF3 or Cr2O3 as catalysts: (1) (2) (3) In addition, the cis-trans equilibria of both CF3CF=CFCl and CF3CCl=CFCl were able to be derived from the reaction data.The experimental thermochemical properties for reactions (1), (2) and (3) were compared with property values calculated using a well-known approximation method.A study of the exchange equilibria of chlorofluoroethylenes failed to yield accurate thermochemical values due to significant side reactions.However, a brief study of the mechanism of a catalytic disproportionation of CF2=CFCl: was carried out.

Full text of DOI:10.1016/S0022-1139(00)82180-6

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HALOGEN EXCHANGE EQUILIBRIA OF CHLOROFLUOROOLEFINS

DOI: 10.1016/S0022-1139(00)82180-6

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0022-1139(00)82180-6

Full text of DOI:10.1016/S0022-1139(00)82180-6

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