REGIOSELECTIVITY OF NUCLEOPHILIC ADDITIONS TO TRICARBONYL5-2-METHYL-2,4-CYCLOHEXADIEN-1-YL>IRON(1+)PF6-: TEMPERATURE DEPENDENCE OF HYDRIDE REDUCTIONS

DOI: 10.1016/S0022-328X(00)80990-0

Source and publish data:

Journal of Organometallic Chemistry p. 91 - 104 (1981)

Update date:2022-08-02

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Authors:

Birch, Arthur J.

Stephenson, G. Richard

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Article abstract of DOI:10.1016/S0022-328X(00)80990-0

Reduction of <(η⁵-CH3C6H6)Fe(CO)3>⁺PF6^- by NaBH4, LiBH4, LiEt3BH and KBu^s₃BH becomes less regioselective at lower temperatures.Regioselectivity of reduction by 9-BBN, however, improves as the temperat

Full text of DOI:10.1016/S0022-328X(00)80990-0

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