Chemistry Letters p. 897 - 900 (1994)
Update date:2022-08-05
Topics:
Miyake, Hideyoshi
Yamamura, Kimiaki
1-(Tributylstannyl)-2-alkene reacts with a solution of an aldehyde and BuSnCl3 to give (Z)-homoallylic alcohol.Z-Selective 2-methyl-2-butenylation can be accomplished by using (Z)-2-methyl-1-(tributylstannyl)-2-butene instead of 1-(tributylstannyl)-2-alkene.This reaction is useful as a new method to make (Z)-double bond.An application ot the present method for a synthesis of pheromones is also described.
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