Preparation of Methoxy-substituted Diaryl Ketone Anils via Phenyliminodimagnesium Intermediate

DOI: 10.1246/bcsj.53.281

Source and publish data:

Bulletin of the Chemical Society of Japan p. 281 - 282 (1980)

Update date:2022-08-05

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Authors:

Okubo, Masao

Ueda, Sonoko

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Article abstract of DOI:10.1246/bcsj.53.281

Phenyliminodimagnesium reagent (PhN(MgBr)2) and its o- and p-methoxy derivatives, prepared in THF by treatment of anilines with EtMgBr, were found to be effective for condensation with benzopheneones and fluorenone.The corresponding anils (N-(diarylmethylene)anilines) were prepared in good yields.

Full text of DOI:10.1246/bcsj.53.281

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