FRONTIER ORBITAL CONTROLLED CYCLOADDITION OF 2-AZAPENTALENES

DOI: 10.1016/S0040-4039(00)93619-0

Source and publish data:

Tetrahedron Letters p. 41 - 44 (1980)

Update date:2022-08-05

Topics:

Authors:

Hafner, Klaus

Klaes, Heinz-Gerd

Boehm, Michael C.

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Article abstract of DOI:10.1016/S0040-4039(00)93619-0

It is shown that cycloadditions of 1,3-bis(dimethylamino)pentalenes and their 2-azaanalogues with activated alklines are frontier orbital controlled whereas protonation is charge controlled.

Full text of DOI:10.1016/S0040-4039(00)93619-0

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