Tetrahedron Letters p. 503 - 506 (1980)
Update date:2022-07-30
Topics:
Hassdenteufel, Juergen Rolf
Hanack, Michael
The α-alkynyl vinyl triflates (3) are synthesized and the solvolyses reactions studied in different solvents.The solvolysis products and kinetic data indicate, that the hitherto unknown triple bond stabilized vinyl cation 2a <*> 2b is formed as an intermediate.
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Doi:10.1016/S0040-4039(01)86298-5
(1979)Doi:10.1016/0031-9422(80)83213-4
(1980)Doi:10.1016/0040-4020(80)80019-6
(1980)Doi:10.1016/0022-5088(80)90224-6
(1980)Doi:10.1021/ja01266a015
(1939)Doi:10.1021/jo01310a016
(1980)
