Preparation of β-Hydroxy-α-phenylthio Esters via Condensation of Aldehydes with α-Phenylthio Ester Enolate Anions

DOI: 10.1021/jo01306a002

Source and publish data:

Journal of Organic Chemistry p. 3549 - 3554 (1980)

Update date:2022-08-04

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Authors:

Hoye, Thomas R.

Kurth, Mark J.

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Article abstract of DOI:10.1021/jo01306a002

The lithium enolates of α-phenylthio esters 5 react with aldehydes 6 to give good yields of diastereomeric aldol products 7 and 8 provided that anhydrous zinc chloride is first added to the enolate solution.The threo or erythro nature of several of the al

Full text of DOI:10.1021/jo01306a002

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