Journal of Medicinal Chemistry p. 722 - 726 (1980)
Update date:2022-07-29
Topics:
Konopelski, Joseph P.
Djerassi, Carl
The syntheses of phenylselenium-substituted progesterone <21- (1) and 17α-(phenylseleno)progesterone (2)> and testosterone <16β- (3) and 16α-(phenylseleno)testosterone (4)> derivatives are described, along with data which help to establish the stereochemistry of the substituents in the testosterone molecules.Except for 21-(phenylseleno)progesterone, the molecules exhibit greatly reduced receptor-binding capabilities.
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