Stereospecific Synthesis of Diastereoisomerically Pure (-)-(RP)-O-Mentyl Methylphenylphosphinite and Ethylphenylphosphinite: Key Intermediates in Synthesis of Chiral Tertiary Phosphines

DOI: 10.1039/c39800000024

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 24 - 25 (1980)

Update date:2022-08-05

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Authors:

Omelanczuk, Jan

Perlikowska, Wieslawa

Mikolajczyk, Marian

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Article abstract of DOI:10.1039/c39800000024

The reaction of the diastereoisomerically pure (-)-(R_P)-O-mentyl methylphenylphosphinite (9) and (-)-(R_P)-O-mentyl ethylphenylphosphinite (2) with organolithium reagents has been found to give chiral tertiary phosphines (10) and (11) with a very high optical purity.

Full text of DOI:10.1039/c39800000024

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