Stereospecific Synthesis of Diastereoisomerically Pure (-)-(RP)-O-Mentyl Methylphenylphosphinite and Ethylphenylphosphinite: Key Intermediates in Synthesis of Chiral Tertiary Phosphines

DOI: 10.1039/c39800000024

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 24 - 25 (1980)

Update date:2022-08-05

Topics:

Authors:

Omelanczuk, Jan

Perlikowska, Wieslawa

Mikolajczyk, Marian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000024

The reaction of the diastereoisomerically pure (-)-(R_P)-O-mentyl methylphenylphosphinite (9) and (-)-(R_P)-O-mentyl ethylphenylphosphinite (2) with organolithium reagents has been found to give chiral tertiary phosphines (10) and (11) with a very high optical purity.

Full text of DOI:10.1039/c39800000024

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(R)-Butyl-ethyl-phenyl-phosphane

Cas No:74158-48-8

R&D Labs maybe for 74158-48-8

MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA

Relevant to this article

E/Z equilibrium in tertiary amides. Part 2: N-acyl-N′-arylhexahydropyrimidines

Doi:10.1016/j.molstruc.2009.12.011
(2010)
Synthesis and characterization of a class of donor-acceptor conjugated molecules: Experiments and theoretical calculations

Doi:10.1021/jp909635g
(2010)
Novel Uncatalyzed Thermal Pummerer Rearrangements

Doi:10.1021/jo00074a051
(1993)
Water-soluble benzo- and naphtho-thiadiazole-based bistriazoles and their metal-binding properties

Doi:10.1039/b920484a
(2010)
Structure-activity relationship for thiohydantoin androgen receptor antagonists for castration-resistant prostate cancer (CRPC)

Doi:10.1021/jm901488g
(2010)
Metal complexes of 4,11-dimethyl-1,4,8,11-tetraazacyclotetradecane-1, 8bis(methylphosphonic acid) - Thermodynamic and formation/decomplexation kinetic studies

Doi:10.1002/ejic.200900358
(2009)

Article Doi