Journal of the Chemical Society. Perkin transactions II p. 306 - 312 (1980)
Update date:2022-08-05
Topics:
Morgan, Roger P.
Derrick, Peter J.
Loudon, Alexander G.
The kinetics of decomposition of pentanal and its monomethyl homologues, including hexanal, have been studied as a function of time following field ionisation (FI).With the aid of these results and other energetic measurements, the McLafferty rearrangement in the case of hexanal is shown to occur by a stepwise mechanism.
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