Monatshefte fur Chemie p. 81 - 92 (1980)
Update date:2022-08-02
Topics: Fries rearrangement Ketoesters
Martin, Robert
Gros, Nicole
Boehmer, Volker
Kaemmerer, Hermann
During the Fries rearrangement of o- and p-methoxy phenyl acetates with AlCl3 in nitromethane at 20 deg C substitution occurs mainly in the p-position of the phenolic residue to yield p-acylphenols.Larger quantities of o-acylphenols are obtained only, if
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