Cyclization of Dinitrophenyl tert-Butyl Trithiocarbonates. A Novel Synthesis of Nitro-1,3-benzodithiole-2-thiones

DOI: 10.1021/jo01308a020

Source and publish data:

Journal of Organic Chemistry p. 4041 - 4044 (1980)

Update date:2022-08-02

Topics:

Authors:

Rasheed, Khalid

Warkentin, James D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01308a020

Reaction of the sodium salt of tert-butyl trithiocarbonic acid with chlorodinitrobenzenes yields dinitrophenyl tert-butyl trithiocarbonates.The latter cyclize on heating in glacial acetic acid to nitro-1,3-benzodithiole-2-thiones.

Full text of DOI:10.1021/jo01308a020

Products guided by the article

Product name:n-Butyl 2,4-dinitro-6-(trifluoromethyl)phenyl Trithiocarbonate

Cas No:74512-02-0

R&D Labs maybe for 74512-02-0

Shouguang Nuomeng Chemical Co., Ltd.

Contact:+86-536-5119508/18363669993

Address:Hou Zhen Industrial Park, Shouguang, Shandong, China
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
Sino-Japan Chemical Co., Ltd.

website:http://www.sjc.com.tw

Contact:(886) 2-2396-6223

Address:14Fl., No. 99. Sec. 2, Jen Ai Road
Hubei Honch Pharmaceutical Co.,Ltd

Contact:86-713-7222018

Address:Li Shizhen Pharmaceutical Industry park, Qichun County, Hubei Province,China

Relevant to this article

Diphenylindane-based proteomimetics reproduce the projection of the i, i+3, i+4, and i+7 residues on an α-helix

Doi:10.1021/ol052956q
(2006)
High-yield synthesis of substituted and unsubstituted pyridinium salts containing a 4-oxothiazolidine moiety

Doi:10.1055/s-2008-1067113
(2008)
Self-assembly of an alkali metal cluster stabilized by a new flexidentate metalloligand: formation and structure of heterobimetallic Na-Mo and Cs-Mo 2D networks

Doi:10.1002/ejic.200500601
(2005)
Stereoselective synthesis of spirocyclic oxindoles based on a one-pot Ullmann coupling/Claisen rearrangement and its application to the synthesis of a hexahydropyrrolo[2,3-b]indole alkaloid

Doi:10.1016/j.tet.2013.08.057
(2013)
Doi:10.1021/ja01580a055
(1957)
Synthesis of 5,6-Dimethyl-9-methoxy-1-phenyl-6H-pyrido[4,3-b]carbazole derivatives and their cytotoxic activity

Doi:10.1002/ardp.200500141
(2005)

Article Doi