Journal of the American Chemical Society p. 3424 - 3430 (1980)
Update date:2022-08-05
Topics:
Fehlner, Thomas P.
The photolysis of the nido ferraborane, B4H8Fe(CO)3, in the presence of an alkyne, RCCR, produces a good yield of the tetracarbon carborane, R4C4B4H4.The C-tetramethyl derivative of this new carborane has been characterized primarily by mass and NMR spectroscopy.An intermediate in the formation of this carborane, (CH3)4C4B4H4Fe(CO)3, has been isolated and partially characterized.Evidence is also presented for the formation of six- and eight-carbon carboranes in this system.Finally, the photolytic behavior of the ferraborane is contrasted with that of the isoelectronic organometallic compond, C4H4Fe(CO)3.
Sichuan Highlight Fine Chemicals Co., Ltd.
Contact:+86-28-8525 1605
Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Ningxia Soochow Agrochemical Limited Company
Contact:(+86）0512 6320 8190
Address:wujiang
Forsman Scientific(Beijing)co.,Ltd.
Contact:+86-10-64646565
Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Beijing Cooperate Pharmaceutical Co.,Ltd
website:http://www.cooperate-pharm.com/
Contact:86-01060279497
Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Doi:10.1039/P19800000705
(1980)Doi:10.1021/tx990126d
(2000)Doi:10.1021/jo01311a032
(1980)Doi:10.1016/0040-4020(80)80055-X
(1980)Doi:10.1016/S0040-4039(00)77832-4
(1980)Doi:10.1021/ja01548a061
(1958)
