Journal of the American Chemical Society p. 3424 - 3430 (1980)
Update date:2022-08-05
Topics:
Fehlner, Thomas P.
The photolysis of the nido ferraborane, B4H8Fe(CO)3, in the presence of an alkyne, RCCR, produces a good yield of the tetracarbon carborane, R4C4B4H4.The C-tetramethyl derivative of this new carborane has been characterized primarily by mass and NMR spectroscopy.An intermediate in the formation of this carborane, (CH3)4C4B4H4Fe(CO)3, has been isolated and partially characterized.Evidence is also presented for the formation of six- and eight-carbon carboranes in this system.Finally, the photolytic behavior of the ferraborane is contrasted with that of the isoelectronic organometallic compond, C4H4Fe(CO)3.
Nanjing Chemipioneer Pharma&Tech Co.,Ltd
website:http://www.chemipioneer.com.cn
Contact:+86-25-52685700
Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
Hangzhou innopharma technology Co,.Ltd.(expird)
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
qingdao goldenchem imp and exp co.,ltd.
Contact:532-55579246
Address:no.62 ,haier road laoshan distirct
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
Shuanghe Bio-Technology Limited(expird)
Contact:+86-571-61710758,18968016640
Address:Jinqiao north road 916# Fuyang
Doi:10.1039/P19800000705
(1980)Doi:10.1021/tx990126d
(2000)Doi:10.1021/jo01311a032
(1980)Doi:10.1016/0040-4020(80)80055-X
(1980)Doi:10.1016/S0040-4039(00)77832-4
(1980)Doi:10.1021/ja01548a061
(1958)
