Deoxygenation of allylic alcohols to terminal olefins via stannylation/destannylation

DOI: 10.1016/S0040-4039(00)77832-4

Source and publish data:

Tetrahedron Letters p. 1767 - 1770 (1980)

Update date:2022-08-05

Topics:

Authors:

Ueno, Yoshio

Sano, Hiroshi

Okawara, Makoto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77832-4

Deoxygenation of allylic alcohols to terminal olefins was performed via three steps; 1) [3,3]-sigmatropic rearrangement of O-allylxanthates, 2) the successive stannolysis with tributyltin hydride yielding allylic stannanes, and 3) final protolysis of allylic stannanes to terminal olefins.

Full text of DOI:10.1016/S0040-4039(00)77832-4

Products guided by the article

Product name:Dithiocarbonic acid S-methyl ester S-(2-methyl-1-phenethyl-allyl) ester

Cas No:74940-35-5

R&D Labs maybe for 74940-35-5

Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang

Relevant to this article

Probing the utility of palladium complexes supported by morpholine-functionalized N -heterocyclic carbene ligands in Buchwald-Hartwig amination

Doi:10.1139/cjc-2013-0132
(2013)
Highly efficient α-C-sialylation promoted by (p-Tol) ₂SO/Tf₂O with N-acetyl-5-N,4-O-oxazolidione protected thiosialoside as donor

Doi:10.1039/c3ob40876k
(2013)
Robust cyclometallated Ir(iii) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions

Doi:10.1039/c3cc44567d
(2013)
Preparation, characterization, and properties of poly(aryl ether sulfone) systems with double-decker silsesquioxane in the main chains by reactive blending

Doi:10.1002/pola.27058
(2014)
New regio-selective method of combinatorial synthesis of substituted thiophenes, thieno[3,2-b]pyridines and other heterocycles via combination of 'domino'-type reactions

Doi:10.1016/j.tet.2013.09.025
(2013)
A general synthesis of bis-α-acyloxy-1,4- and -1,5-diketones through catalytic oxidative opening of acylated THF and THP diols

Doi:10.1002/ejoc.201201554
(2013)

Article Doi