Deoxygenation of allylic alcohols to terminal olefins via stannylation/destannylation

DOI: 10.1016/S0040-4039(00)77832-4

Source and publish data:

Tetrahedron Letters p. 1767 - 1770 (1980)

Update date:2022-08-05

Topics:

Authors:

Ueno, Yoshio

Sano, Hiroshi

Okawara, Makoto

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Article abstract of DOI:10.1016/S0040-4039(00)77832-4

Deoxygenation of allylic alcohols to terminal olefins was performed via three steps; 1) [3,3]-sigmatropic rearrangement of O-allylxanthates, 2) the successive stannolysis with tributyltin hydride yielding allylic stannanes, and 3) final protolysis of allylic stannanes to terminal olefins.

Full text of DOI:10.1016/S0040-4039(00)77832-4

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